The objective of this experiment is to verify that 1 calorie = 4.186 joules.
A calorimeter with electric heating element, a dc power source, two multi-meters, a thermometer, a few connecting wires, water, a stop watch, and a mass scale
In the past several decades, it has been repeatedly verified by many scientists and experimenters that when 1 calorie of heat is converted to mechanical or electric work, 4.18 J of work is generated and vice versa.
1 cal = 4.18 J
The heating element in a calorimeter may be connected to a power source for a certain period during which electric work (energy) causes an increase in temperature of the fluid in the calorimeter. The result is conversion of electric work to heat energy. To calculate the energy delivered to the calorimeter, the formula for power may be used:
P = W / t or W = Pt
Since electric power is P = V I, the above equation, which gives the electric energy consumption, becomes:
W = V I t (1)
On one hand, by measuring the applied voltage V, the effective current I, and the consumption time t, the electric energy delivered to the calorimeter can be calculated by this formula. On the other hand, by measuring the initial and final temperatures of the calorimeter, as well as the masses of the water, the aluminum container, and the heating element (including its attachments), the amount of heat generated can be calculated. Of course, the specific heats of water, aluminum, as well as the heating element must be obtained from your physics text or from a handbook. The heat absorbed in the calorimeter is
Qtotal = Qwater + QAl + QBrass
Qtotal = mw cw (ΔT) + mAl cAL (ΔT) + mBr cBr (ΔT), or
Qtotal = [ mw cw + mAl cAL + mBr cBr ] (ΔT) (2)
This equation calculates the total heat generated in calories as a result of electric work done in the heating element in joules. Both values can be calculated in order to determine how many joules one calorie can generate or vice versa.
Using a zeroed mass scale, measure the mass of the internal container of the calorimeter (mAl) first, and then measure it again when it is 1/3 full with clean water. This way, the mass of added water (mw) can be calculated easily. Disassemble the heating element assembly from the lid of the calorimeter and measure its mass mBr with a balance scale. Reassemble the heating element into the lid. If the mass is predetermined, skip this step. Place the thermometer in the calorimeter through the hole in the lid, and wait until thermal equilibrium is reached. Record this initial temperature (Ti). With the electric power source off, connect the calorimeter to the source in series with an ammeter.
Note that the ammeter in this experiment will measure currents that exceed 200 mA. There is a third terminal on the multi-meter that is specially used for this purpose. The positive wire (red) must be pulled out of the usual positive terminal on the meter and inserted into this third terminal, which is labeled (+10 A or 10,000 mA). The negative wire (black) remains in the terminal that is labeled “Common.”
Now that you have connected the calorimeter, ammeter (in +10 A position), and power source in series, it is almost time to turn the power on. The voltmeter on the power source is not accurate. It is better to measure the voltage of the power source with a separate meter. A typical diagram of the experimental arrangement is shown below:
Now disconnect the ammeter from the power source for the purpose of first selecting an operating voltage. Turn on the power source, and set the voltage to not more than 6 V. Turn off the power (without changing the voltage setting), and reconnect the ammeter to the power source. Re-check the initial temperature (Ti). When you are ready to measure time, turn on the power source.
It is better to write down the values of V and I every 30 seconds, and then calculate a mean value for each, and use those mean values in the calculation of consumed electric energy (W = V I t). This will compensate (to some degree) for voltage fluctuations of the power source due to causes out of our control. The following table may be used for this purpose:
It is a good idea to keep shaking the calorimeter gently (or stirring the water), once every minute to facilitate heat distribution. After the desired period of heating is reached, turn off the power source and wait for the temperature to reach its maximum. Record this maximum as Tf.
cw = 1.000 cal/(g C˚)
cBr = 0.0924 cal/(g C˚)
cAl = 0.215 cal/(g C˚)
t = 12.50 minutes
(W/Q)accepted = 4.18 J/cal
Measured: mw , mBr , mAl , Ti , Tf , V , I
Use equations (1) and (2) to calculate W and Q. Then find (W/Q)measured .
Comparison of the Results:
The accepted and measured values of (W/Q) may be used to obtain a percent error.
Conclusion: To be explained by students
Discussion: To be explained by students